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Players in juniors can and frequently do take college courses for credit before enrolling in college. The issue is that they cannot take a full course load because that will burn a year of their 5 years of athletic eligibility to play 4 years in college. The reason the above posters were mentioning discussions with the players’ colleges is because each college determines what a full load is and whether the credits are transferable.
Here are some of the basics: http://collegehockeyinc.com/articles/2014/09/taking-college-classes-juniors.php